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Oil Analysis - Chemistry

Oil Analysis - Chemistry

The primary application for lube oil analysis is to ensure that the oil meets the lubrication requirements of the machine.


The chemistry of a lubricant is typically looked at in two ways:


1) the quality of the base oil and its properties 

2) the additives and their ability to perform

Oil Quality

Tests Performed

Appearance

Colour

Odour

Viscosity (cSt)

Viscosity Index

Total Acid Number (TAN) or Acidity

Total Base Number (TBN)

Water Content

Air Release

Asphaltenes

Cold Cranking Simulator (Winter Grade Viscosities)

Hydrolytic Stability

Total Insolubles

Chlorine

Flash Point

Pour Point

Foaming

Free Water

Glycol

Oxidation

Nitration

RPVOT

RULer

Rust Prevention

Sediment (Particulate Matter)

Spectrographic Analysis

Soot

Varnish Number (MPC)

Water Separation or Demulsibility

Additives

Antimony

Antimony

Antimony

Antimony element symbol and atomic number

Used as a multifunctional additive in organic antimony compounds such as Antimony diakyl dithiocarbamates (sometimes denoted as SbDTC or ADD).

Known to perform as: anti-scuffing (EW) agents, anti-wear (AW) agents, oxidation inhibitors, copper-lead corrosion inhibitors and rust inhibitors.

Barium

Antimony

Antimony

Barium element symbol and atomic number

Sources: Corrosion Inhibitors, Detergents, Rust Inhibitors. 

Boron

Antimony

Calcium

Boron element symbol and atomic number

Sources: Corrosion Inhibitor additive and Antiwear/Antioxidant additive 

Can indicate coolant leak or grease contamination.

Calcium

Molybdenum

Calcium

Calcium element symbol and atomic number

Sources: Detergent/dispersant additive, Alkaline reserve additive for high sulphur fuelled engines. 

Can be from grease contamination.

Magnesium

Molybdenum

Molybdenum

Magnesium element symbol and atomic number

Sources: Detergent/dispersive additive.

Can also be found as an alloying element in steel.

Molybdenum

Molybdenum

Molybdenum

Molybdenum element symbol and atomic number

Sources: Solid/liquid antiwear additive. 

Also used as an alloy in bearing and piston rings.

Phosphorus

Phosphorus

Phosphorus

Phosphorous element symbol and atomic number

Sources: Antiwear additives, Corrosion inhibitors, Anti-oxidants additives, 

EP additives.

Sulphur

Phosphorus

Phosphorus

Sulfur element symbol and atomic number

Sulphur present in fuel or engine oil during combustion can combine with water produced during the combustion process to form sulphuric acid (battery acid) which can cause corrosion to engines. Engine oil lubricants thus have special antacid additives (Base Number) to neutralize the acids (Acid Number).

Zinc

Phosphorus

Zinc

Zinc element symbol and atomic number

Sources: Antiwear additive (Zinc dialkly dithiophosphate – ZDDP), Corrosion inhibitors, Anti-oxidants.

Also used for alloying element for bearings, thrust washers and galvanized cases.

OIL ANALYSIS
ROUTINE CONDITION MONITORING

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